Cyclohexane-1,2-diammonium bis(pyridine-2-carboxylate)

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Metabolism of benzoate, cyclohex-1-ene carboxylate, and cyclohexane carboxylate by "Syntrophus aciditrophicus" strain SB in syntrophic association with H(2)-using microorganisms.

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Cyclo­hexane-1,2-diammonium bis­(pyridine-2-carboxyl­ate)

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Hexane-1,6-diammonium bis­(pyridine-2-carboxyl­ate)

The title compound, C(6)H(18)N(2) (2+)·2C(6)H(4)NO(2) (-), consists of a doubly protonated hexa-methyl-enediammonium dication and two pyridine-2-carboxyl-ate anions. These ions inter-act by means of inter-molecular N-H⋯O and N-H⋯N hydrogen bonds to form a two-dimensional array. The carboxyl-ate groups of the anions appear to be delocalized on the basis of the C-O bond lengths.

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N,N′-Bis[2-(methoxycarbonyl)ethyl]ethane-1,2-diammonium dichloride

In the crystal structure of the title compound, C(10)H(22)N(2)O(4) (2+)·2Cl(-) or (H(2)Me(2)eddp)Cl(2) (H(2)Me(2)eddp(2+) is the dimethyl N,N'-di-3-propane-carboxylato-ethane-1,2-diyldiimin-ium cation), the packing is stabilized by an infinite two-dimensional ⋯Cl⋯H-N-H⋯Cl⋯ hydrogen-bonding network. In addition, short C-H⋯Cl contacts are observed.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809038689